(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Me-BPE-Rh

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Catalog Number
ACM305818671
Product Name
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Me-BPE-Rh
Structure
Structure
CAS
305818-67-1
Category
Heterocyclic Organic Compound
Synonyms
305818-67-1;1,2-Bis[(2R,5R)-2,5-(dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate;(R,R)-Me-BPE-Rh;DTXSID30584863;PUBCHEM_16218294;MFCD04038741;J-018028;(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate;
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane;rhodium;tetrafluoroborate;
Molecular Weight
556.219g/mol
Molecular Formula
C22H40BF4P2Rh-;
Canonical SMILES
[B-](F)(F)(F)F.CC1CCC(P1CCP2C(CCC2C)C)C.C1CC=CCCC=C1.[Rh];
InChI
InChI=1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m1.../s1;
InChI Key
LKVIVYCYPYTYSO-ZTCBNWEGSA-N;
Application
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Complexity
277
Covalently-Bonded Unit Count
4
Defined Atom Stereocenter Count
4
Defined Bond Stereocenter Count
2
Exact Mass
556.169g/mol
Formal Charge
-1
H-Bond Acceptor
5
Heavy Atom Count
30
Monoisotopic Mass
556.169g/mol
Rotatable Bond Count
3
Topological Polar Surface Area
0A^2
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