1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene

• CAS: 147253-67-6
• Catalog Number: ACM147253676
• Category: Other Products
• Molecular Weight: 306.37g/mol
• Molecular Formula: C18H28P2
• Synonyms: (R,R)-1,2-Bis(2,5-dimethylphospholano)benzene; DTXSID20163641; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, kanata purity; H5W03D1HAQ; UNII-H5W03D1HAQ; (R,R)-Me-DUPHOS; AJNZWRKTWQLAJK-KLHDSHLOSA-N; (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene; (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, >=95.0%
• IUPAC Name: (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane
• Canonical SMILES: CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C
• InChI: InChI=1S/C18H28P2/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4/h5-8,13-16H,9-12H2,1-4H3/t13-,14-,15-,16-/m1/s1
• InChI Key: AJNZWRKTWQLAJK-KLHDSHLOSA-N
• Application: The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted cetamidoacrylates and enol acetates yielding products of high enantiomeric excesses.; ; Efficient ligand for the asymmetric hydrogenation of imines, enamines, and enamides.; ; Asymmetric hydrogenation of vinyl alcohols.; ; Catalyst used for the asymmetric hydrogenation of enol phosphonates.; ; Asymmetric hydrogenation of allylic alcohols.; ; Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.; ; Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.; ; Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
• Complexity: 277
• Covalently-Bonded Unit Count: 1
• Defined Atom Stereocenter Count: 4
• EC Number: 604-579-6
• Exact Mass: 306.167g/mol
• Heavy Atom Count: 20
• Monoisotopic Mass: 306.167g/mol
• Rotatable Bond Count: 2
• Topological Polar Surface Area: 0A^2
• UNII: H5W03D1HAQ