Catalog Number
ACM147253676
Product Name
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene
Category
Heterocyclic Organic Compound
Synonyms
(R,R)-1,2-Bis(2,5-dimethylphospholano)benzene; DTXSID20163641; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, kanata purity; H5W03D1HAQ; UNII-H5W03D1HAQ; (R,R)-Me-DUPHOS; AJNZWRKTWQLAJK-KLHDSHLOSA-N; (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene; (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene; (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene, >=95.0%;
IUPAC Name
(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane;
Molecular Weight
306.37g/mol
Molecular Formula
C18H28P2;
Canonical SMILES
CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C;
InChI
InChI=1S/C18H28P2/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4/h5-8,13-16H,9-12H2,1-4H3/t13-,14-,15-,16-/m1/s1;
InChI Key
AJNZWRKTWQLAJK-KLHDSHLOSA-N;
Application
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted cetamidoacrylates and enol acetates yielding products of high enantiomeric excesses.
Efficient ligand for the asymmetric hydrogenation of imines, enamines, and enamides.
Asymmetric hydrogenation of vinyl alcohols.
Catalyst used for the asymmetric hydrogenation of enol phosphonates.
Asymmetric hydrogenation of allylic alcohols.
Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
Covalently-Bonded Unit Count
1
Defined Atom Stereocenter Count
4
Monoisotopic Mass
306.167g/mol
Topological Polar Surface Area
0A^2
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