CAS
225937-10-0 Purity
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225937-10-0 Purity
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(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Et-DUPHOS-Rh
CAS
228121-39-9
Catalog Number
ACM228121399
Category
Other Products
Molecular Weight
660.371g/mol
Molecular Formula
C30H48BF4P2Rh-;
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Specification
Synonyms
228121-39-9;[(R,R)Ethyl-DuPhosRh(COD)]BF4;MFCD01862464;DTXSID50459685;(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(l) tetrafluoroborate;J-014866;1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane;rhodium;tetrafluoroborate;
SMILES
[B-](F)(F)(F)F.CCC1CCC(P1C2=CC=CC=C2P3C(CCC3CC)CC)CC.C1CC=CCCC=C1.[Rh];
InChI
InChI=1S/C22H36P2.C8H12.BF4.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m1.../s1;
InChI Key
XIOPHSBHVOCZMM-KYOOHHHUSA-N;
Application
Ligand used in asymmetric hydrogenation of 2-methylenesuccinamic acid.
Ligand used for the Rh-catalyzed asymmetric hydrogenation of α-aminomethylacrylates.
Ligand used for the Rh-catalyzed asymmetric hydrogenation of α-aminomethylacrylates.
Complexity
414
Covalently-Bonded Unit Count
4
Defined Atom Stereocenter Count
4
Defined Bond Stereocenter Count
2
Exact Mass
660.232g/mol
Formal Charge
-1
H-Bond Acceptor
5
Heavy Atom Count
38
Monoisotopic Mass
660.232g/mol
Rotatable Bond Count
6
Topological Polar Surface Area
0A^2
December 15, 2022
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