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Home > Product > Boronic Compounds > Other > Pinacolborane

Pinacolborane

Catalog Number
ACM25015638
Product Name
Pinacolborane
Structure
CAS Number
25015-63-8
Synonyms
4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;PINACOLBORANE;Pinacolboronane;4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE,1M SOLUTION IN TETRAHYDROFURAN;1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-;4,4,5,5-tetramethyl-1,3,2-dioxaborolane solution;Pinacolborane(PINB);4,4,5,5-TETRAMETHYL-1,3,2-DIOXA-&
Molecular Weight
127.98
Molecular Formula
C6H13BO2
Boiling Point
42-43°C50mm Hg(lit.)
Flash Point
41°F
Density
0.882g/mL at 25°C(lit.)
Symbol
GHS02,GHS07,GHS08
Safty Description
16-43-8-37/39-26-33-29-36/37
Hazard Statements
F,Xi,Xn
Supplemental Hazard Statements
H225-H261-H302-H319-H335-H351-H333
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1Reactivity of a Molecular Magnesium Hydride Featuring a Terminal Magnesium-Hydrogen Bond.

Schnitzler S1, Spaniol TP1, Okuda J1.

Inorg Chem. 2016 Dec 19;55(24):12997-13006. Epub 2016 Dec 1.

The reactivity of the molecular magnesium hydride [Mg(Me3TACD·AliBu3)H] (1) featuring a terminal magnesium-hydrogen bond and an NNNN-type macrocyclic ligand, Me3TACD ((Me3TACD)H = Me3[12]aneN4 = 1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane), can be grouped into protonolysis, oxidation, hydrometalation, (insertion), and hydride ion. Protonolysis of 1 with weak Brønsted acids HX such as terminal acetylenes, amines, silanols, and silanes gave the corresponding derivatives [Mg(Me3TACD·AliBu3)X] (X = C≡CPh, 3; HN(3,5-Me2-C6H3), 4; OSiMe3, 5; OSiPh3, 6; Cl, 7; Br, 8). Read More

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Tel:1-201-478-8534
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