Ahn S, Thornburg NE, Li Z, Wang TC, Gallington LC1, Chapman KW1, Notestein JM, Hupp JT, Farha OK2.
Inorg Chem. 2016 Nov 21;55(22):11954-11961. Epub 2016 Oct 31.Developing structurally well-defined, supported oxide catalysts remains a significant challenge. Here, we report the grafting of Nb(V) oxide sites onto the nodes of the Zr-based metal organic framework (MOF) NU-1000 as a stable, well-defined catalyst support. Nb(V) oxide was deposited with loadings up to 1.6 mmol/g via two postsynthetic methods: atomic layer deposition in a MOF, and solution-phase ... Read More