Schnapperelle I1, Breitenlechner S1, Bach T2.
Chemistry. 2015 Dec 7;21(50):18407-16. doi: 10.1002/chem.201503067. Epub 2015 Oct 30.Reaction orders for the key components in the palladium(II)-catalyzed oxidative cross-coupling between phenylboronic acid and ethyl thiophen-3-yl acetate were obtained by the method of initial rates. It turned out that the reaction rate not only depended on the concentration of palladium trifluoroacetate (reaction order: 0.97) and phenylboronic acid (reaction order: 1.26), but also on the concentra ... Read More