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Home > Product > Boronic Compounds > Other > Palladium(II) Acetate

Palladium(II) Acetate

Catalog Number
ACM3375313
Product Name
Palladium(II) Acetate
Structure
CAS Number
3375-31-3
EC Number
222-164-4
IUPAC Name
palladium(2+);diacetate;
Synonyms
Palladium(2+) acetate; Acetic acid, palladium salt; palladium(II)diacetate; diacetoxy palladium; palladium-(II)-acetate; palladium (II) acetat; AB1002371; Pd(acetate)2; palladiumdiacetate; AK-98692;
Molecular Weight
224.508g/mol
Exact Mass
223.93g/mol
Molecular Formula
C4H6O4Pd;
SMILES
CC(=O)[O-].CC(=O)[O-].[Pd+2];
InChIKey
YJVFFLUZDVXJQI-UHFFFAOYSA-L;
H-Bond Acceptor
4
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1Theoretical Studies on Palladium-Mediated Enantioselective C-H Iodination.

Zhou MJ1, Yang TL1, Dang L1.

J Org Chem. 2016 Feb 5;81(3):1006-20. doi: 10.1021/acs.joc.5b02571. Epub 2016 Jan 26.

DFT calculations have been carried out to investigate the reaction mechanism for Pd(II)-mediated enantioselective C-H iodination. Iodination of the aryl ortho C-H bond of benzylamines catalyzed by Pd(II) diacetate complexes in the presence of the L-MPAA ligand experiences three main steps: first, C-H bond activation; second, oxidative addition of iodine on Pd(II) and reductive elimination of iodobenzene; third, catalyst regeneration through ligand exchange. Read More

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA