Structure

Manganese triacetate dihydrate

CAS
19513-05-4
Catalog Number
ACM19513054
Category
Micro/NanoElectronics
Molecular Weight
268.1
Molecular Formula
C6H13MnO8

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Specification

Synonyms
Manganese(III) acetate dihydrate
IUPAC Name
Manganese(3+);triacetate;dihydrate
Canonical SMILES
CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].O.O.[Mn+3]
InChI
InChI=1S/3C2H4O2.Mn.2H₂O/c3*1-2(3)4;/h3*1H3,(H,3,4);2*1H2/q;+3;/p-3
InChI Key
ONJSLAKTVIZUQS-UHFFFAOYSA-K
Solubility
Soluble in water and alcohol
Appearance
Pink solid
Application
Manganese triacetate dihydrate is a versatile chemical compound primarily used as a mild and selective oxidizing agent in organic synthesis and materials science. It catalyzes allylic oxidation of a variety of alkenes, particularly in the presence of tert-butylhydroperoxide. This compound is also utilized in radical cyclizations and α-keto-acetoxylation processes. Structurally, it features a coordination complex centered around oxygen with three manganese atoms interconnected by acetate units. While it readily decomposes in cold water due to hydration, it finds significant application in its dihydrate form, which is synthesized through the reaction of potassium permanganate and manganese (II) acetate in acetic acid. Manganese triacetate dihydrate acts efficiently as a single electron oxidant, showcasing its utility in converting alkenes into lactones via acetic acid addition.
Storage
Inert atmosphere,Room Temperature
Complexity
25.5
Exact Mass
267.999085
Hazard Statements
Xn:Harmful;
H-Bond Acceptor
8
H-Bond Donor
2
Heavy Atom Count
15
Monoisotopic Mass
267.999085
Packing Group
III
Safety Description
S26-S37/39
Topological Polar Surface Area
122 Ų
WGK Germany
3
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