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Iodotrimethylplatinum(IV)

Catalog Number
ACM14364933
Product Name
Iodotrimethylplatinum(IV)
Structure
CAS Number
14364-93-3
MDL Number
MFCD00013702
IUPAC Name
carbanide;iodoplatinum
Synonyms
Trimethylplatinumiodide
Category
organic noble metal
Molecular Weight
367.09
Exact Mass
366.94000
Molecular Formula
C3H9IPt
Melting Point
250ÂșC (dec.)
Purity
Pt >53.1%
Appearance
pale yellow powder
SMILES
[CH3-].[CH3-].[CH3-].I[Pt]
InChIKey
ZCSQPOLLUOLHHF-UHFFFAOYSA-M
H-Bond Donor
0
H-Bond Acceptor
3
Symbol
GHS07
Safty Description
26-36/37/39
Hazard Statements
H315-H319-H335
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1Synthesis of trimethylplatinum(IV) complexes with N,N- and N,O-heterocyclic carbene ligands and their reductive C-C elimination reactions.

Lindner R1, Wagner C, Steinborn D.

J Am Chem Soc. 2009 Jul 1;131(25):8861-74. doi: 10.1021/ja901264t.

Reactions of the platinum(IV) complexes [PtMe(3)(OCMe(2))(3)](BF(4)) (1(BF(4))), [(PtMe(3)I)(4)] (2), and [PtMe(3)I(py)(2)] (3) with the N,N-heterocyclic carbene 1,3-dimethylimidazol-2-ylidene (N,N-hc, 4) resulted in a rapid reductive elimination of ethane, yielding platinum(II) complexes [PtMe(N,N-hc)(3)](+) (7), trans-[PtMeI(N,N-hc)(2)] (8), and cis-[PtMe(py)(N,N-hc)(2)](+) (10), respectively. Subsequent substitution of the iodo ligand in 8 by pyridine resulted in the formation of trans-[PtMe(py)(N,N-hc)(2)](CF(3)COO) (9(CF(3)COO)). Read More

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Email:
Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA