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Catalog Number
ACM7783586
Product Name
Germanium(iv)fluoride
Structure
CAS
7783-58-6
Synonyms
GERMANIUM FLUORIDE;GERMANIUM(IV) FLUORIDE;GERMANIUM TETRAFLUORIDE;GeF4;Germane, tetrafluoro-;tetrafluoro-german;tetrafluorogermane;GERMANIUM(IV) FLUORIDE, 99.9+%, ELECTRON IC GRADE
Molecular Formula
F4Ge
Molecular Weight
148.63
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1 The preparation and structure of Ge3F8 - a new mixed-valence fluoride of germanium, a convenient source of GeF2.

Hector AL1, Jolleys A, Levason W, Pugh D, Reid G.

Dalton Trans. 2014 Oct 21;43(39):14514-6. doi: 10.1039/c4dt02265c.

The new binary mixed-valence fluoride of germanium, Ge3F8, has been obtained by heating GeF4 with powdered Ge in an autoclave (390 K/4 bar/48 h). The structure contains pyramidal Ge(II)F3 and octahedral Ge(IV)F6 units, linked by fluoride bridges. The new compound is the missing member of the series (GeF2)n·GeF4 (n = 2, 4, or 6). Sublimation of (GeF2)n·GeF4in vacuo provides a convenient source of GeF2 in ca. 30% overall yield.

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA