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Sulphur Dyes

Sulphur dyes are complex heterocyclic molecules or mixtures formed by melting or boiling organic compounds containing amino or nitro groups with Na-polysulphides and sulphur. They are called sulphur dyes because they all contain sulphur bonds in their molecules. Sulphur dyes are predominantly black, brown and dark blue.

Sulphur dyes are applied in the reduced and dissolved anionic state possessing an affinity for cellulose. Oxidation is carried out after dyeing to restore the structure of the parent nonionic dye; the attachment of sulphur dyes to cellulose is established by the physical force of in situ aggregation of the dye. Sulphur dyes are known for their excellent color fastness, including resistance to washing, light and perspiration. This makes them suitable for applications where durability and color retention are critical. The primary use of sulphur dyes is to dye cotton and regenerated cellulose, in the form of yarn, cloth and garments, or as a component of blends.

Sulphur Dyes

As a professional supplier of high-efficiency dyes, Alfa Chemistry has the ability to provide customers with a comprehensive range of sulphur dyes.

Chemical Structure of Sulphur Dyes

The chemical structure of sulphur dyes is neither clear nor consistent; it is determined by the raw materials and the processes used. Dyes retain sulphur bonds as part of their chromophores and are essentially complex mixtures of polymer molecular species. Among the heterocycles, sulphur in the form of sulphide (-S-), disulphide (-S-S-), and polysulphide (-Sn-) links accounts for a large proportion. The chromogenic system is mainly based on thiazoles, thiazone and thianthrenes, with a few dyes retaining thiazole thioanthraquinones as their chromophore (figure 1) [1].

Various chromophoric systems in sulphur dyesFig. 1 Various chromophoric systems in sulphur dyes

Features of Sulphur Dyes

  1. Sulphur dyes have sulphur bonds in their molecules.
  2. They are completely amorphous and rarely crystalline.
  3. These dyes are insoluble in water, but in the presence of soda ash (Na2CO3) we can dissolve them with sodium sulfite as a reducing agent.
  4. They have no direct affinity for cellulose fibers. Treatment with a reducing agent (e.g., dilute Na2S solution) converts them to soluble ethanol mimicry, making them substantial.
  5. Sulphur dyes have good lightfastness with rating about 4. This light fastness can be improved by post-treatment with metal salts.
  6. These dyes have excellent washing fastness with rating about 3-4. This good washing fastness is due to their large molecular size and insolubility in water.
  7. They are not suitable for wool due to strong alkaline condition.
  8. It is available in powder and soluble forms.
  9. Sulphur dyes are very cheap and readily available.

Alfa Chemistry is committed to becoming a first-class, low-carbon, environmentally friendly dye supplier. Our mission is to provide customers with full specifications of high-quality dyes. We are also constantly expanding our product database to meet the wide range of customer needs. You are welcomed to contact us for more sulphur dyes.

Reference

  1. Chakraborty, J. N. Sulphur dyes. Handbook of Textile and Industrial Dyeing, 2011, 466–485.

It is important to note that our products are for research use only and are not for clinical use.

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