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Catalog Number
ACM14285688
Product Name
Dirhenium decacarbonyl
Structure
CAS
14285-68-8
Synonyms
rhenium(2+); FT-0689501; Y1394; C10H10O10Re2; Rhenium carbonyl; NSC635013; carbon monoxide;
EC Number
238-202-8
IUPAC Name
carbon monoxide;rhenium;
Molecular Formula
C10O10Re2;
Molecular Weight
652.514g/mol
Exact Mass
651.858g/mol
Monoisotopic Mass
653.861g/mol
Topological Polar Surface Area
10A^2
Heavy Atom Count
22
Complexity
10
Covalently-Bonded Unit
12
SMILES
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Re].[Re];
InChI
InChI=1S/10CO.2Re/c10*1-2;;;
InChI Key
ZIZHEHXAMPQGEK-UHFFFAOYSA-N;
H-Bond Acceptor
10
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1 Synthesis, characterization, and gas-phase fragmentation of rhenium-carbonyl complexes bearing imidazol(in)ium-2-dithiocarboxylate ligands.

Beltrán TF1, Zaragoza G2, Delaude L1.

Dalton Trans. 2016 Nov 15;45(45):18346-18355.

Five complexes with the generic formula [ReBr(CO)3(κ2-S,S'-S2C·NHC)] were obtained by reacting [ReBr(CO)5] with a set of representative imidazol(in)ium-2-dithiocarboxylate zwitterions. These ligands are the adducts of N-heterocyclic carbenes (NHCs) and carbon disulfide. The monometallic Re(i) compounds were further coupled with Na[Re(CO)5] to afford bimetallic Re(0) species. Depending on the experi ... Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA