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Catalog Number
ACM7650842
Product Name
Diphenylpropylphosphine
Structure
CAS
7650-84-2
Synonyms
VZ31950; D2630; CC-27135; diphenyl(propyl)phosphane; RTR-024497; SCHEMBL163845; DB-056074; diphenylphosphinopropane; diphenyl(propyl)phosphine; LS-105961;
EC Number
231-607-0
IUPAC Name
diphenyl(propyl)phosphane;
Molecular Formula
C15H17P;
Molecular Weight
228.275g/mol
Rotatable Bond Count
4
Exact Mass
228.107g/mol
Monoisotopic Mass
228.107g/mol
Topological Polar Surface Area
0A^2
Heavy Atom Count
16
Complexity
160
Covalently-Bonded Unit
1
SMILES
CCCP(C1=CC=CC=C1)C2=CC=CC=C2;
InChI
InChI=1S/C15H17P/c1-2-13-16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h3-12H,2,13H2,1H3;
InChI Key
AAXGWYDSLJUQLN-UHFFFAOYSA-N;
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1 Chiral Birch reduced tertiary phosphines: precursors to asymmetric 1,2-cyclohexenebis(tertiary phosphines).

Bulbrook M1, Chu M, Deane K, Doyle RJ, Hinc J, Peterson C, Salem G, Thorman N, Willis AC.

Dalton Trans. 2010 Oct 14;39(38):8878-81. doi: 10.1039/c0dt00648c. Epub 2010 Aug 19.

The first examples of an optically active Birch reduced tertiary phosphine, viz. (R(P))-(cyclohexa-2,5-dienyl)(3-pentyl)phenylphosphine, and successful hydrophosphination of the related racemic ligand (±)-(cyclohexa-2,5-dienyl)(2-propyl)phenylphosphine with PHPh(2) in the presence of KOBu(t) in thf to give a 1,2-cyclohexenebis(tertiary phosphine), viz. (±)-1,2-C(6)H(8)(PPh(2))(PPhPr(i)), are descri ... Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA