CAS
116060-92-5 Purity
96%
116060-92-5 Purity
96%
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Chloro(mesitylene)[(1R,2R)-(-)-2-amino-1,2-diphenylethyl(methylsulfonylamido)]ruthenium(II) RuCl(mesitylene)[(R,R)-MsDpen]
CAS
1160707-20-9
Catalog Number
ACM1160707209
Category
Other Products
Molecular Weight
546.10
Molecular Formula
C24H29ClN2O2RuS
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Specification
Synonyms
[(R,R)-MsDPEN-Ru(mesitylene)Cl], Chloro(mesitylene)[(R,R)-N-methylsulfonyl-1,2-diphenyl-1,2-ethanediamine]ruthenium(II), 1160707-20-9
IUPAC Name
[(1R,2R)-2-amino-1,2-diphenylethyl]-methylsulfonylazanide;chlororuthenium(1+);1,3,5-trimethylbenzene
SMILES
CC1=CC(=CC(=C1)C)C.CS(=O)(=O)[N-]C(C1=CC=CC=C1)C(C2=CC=CC=C2)N.Cl[Ru+]
InChI Key
IACBEXZXCYLFOG-OLVQSPPGSA-M
H-Bond Acceptor
4
H-Bond Donor
1
January 20, 2023
High catalytic efficiency in asymmetric synthesis
In the asymmetric synthesis reaction, chloro(mesitylene)[(1R,2R)-(-)-2-amino-1,2-diphenylethyl(methylsulfonylamido)]ruthenium(II) RuCl(mesitylene) stereoselectively generates Z- olefins under the condition of transfer hydrogenation.
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