2'-(Dimethylamino)-2-biphenylyl-palladium(II) chloride Dinorbornylphosphine complex

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Catalog Number
ACM359803535
Product Name
2'-(Dimethylamino)-2-biphenylyl-palladium(II) chloride Dinorbornylphosphine complex
Structure
Structure
CAS
359803-53-5
Category
Heterocyclic Organic Compound
Synonyms
MFCD03427335; YMZCYRNVJBOOCT-MUGRSZJDSA-M; chloro[2'-(dimethylamino)-2-biphenylyl]palladium (1R,4S)-bicyclo[2.2.1]hept-2-yl[(1S,4R)-bicyclo[2.2.1]hept-2-yl]phosphane; 2'-(Dimethylamino)-2-biphenylyl-palladium(II) chloride Dinorbornylphosphine complex, >=99.0% (C); chloro[2'-(dimethylamino)-2-biphenylyl]palladium 1(1R,4S)-bicyclo[2.2.1]hept-2-yl[(1S,4R)-bicyclo[2.2.1 ]hept-2-yl]phosphane; 2 inverted exclamation marka-(Dimethylamino)-2-biphenylyl-palladium(II) chloride Dinorbornylphosphine complex; chloro[2'-(dimethylamino)-2-biphenylyl]palladium 1(1R,4S)-bicyclo[2.2.1]hept-2-yl[(1S,4R)-bicyclo[2.2.1]hept-2-yl]phosphane;
IUPAC Name
[(1S,4R)-2-bicyclo[2.2.1]heptanyl]-[(1R,4S)-2-bicyclo[2.2.1]heptanyl]phosphane;chloropalladium(1+);N,N-dimethyl-2-phenylaniline;
Molecular Weight
560.455g/mol
Molecular Formula
C28H37ClNPPd;
Canonical SMILES
CN(C)C1=CC=CC=C1C2=CC=CC=[C-]2.C1CC2CC1CC2PC3CC4CCC3C4.Cl[Pd+];
InChI
InChI=1S/C14H14N.C14H23P.ClH.Pd/c1-15(2)14-11-7-6-10-13(14)12-8-4-3-5-9-12;1-3-11-5-9(1)7-13(11)15-14-8-10-2-4-12(14)6-10;;/h3-8,10-11H,1-2H3;9-15H,1-8H2;1H;/q-1;;;+2/p-1/t;9-,10+,11+,12-,13 ,14 ,15 ;;;
InChI Key
JZMMCQBNMQSWGC-MUGRSZJDSA-M;
Application
A new, air and moisture-stable, palladium catalyst useful in a broad scope of C-C and C-N coupling reactions. The highlyactive catalyst can tolerate substrates containing a wide variety of functional groups such as alkyls, alkoxides, ketones, aldehydes, esters, amines, trifluoromethyl and nitro groups.
Complexity
543
Covalently-Bonded Unit Count
3
Defined Atom Stereocenter Count
4
Exact Mass
559.139g/mol
H-Bond Acceptor
2
Heavy Atom Count
32
Monoisotopic Mass
559.139g/mol
Rotatable Bond Count
4
Topological Polar Surface Area
3.2A^2
Undefined Atom Stereocenter Count
2
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