(R)-(+)-XylBINAP

Catalog Number

ACM137219864

Product Name

(R)-(+)-XylBINAP

Structure

CAS

137219-86-4

Category

Heterocyclic Organic Compound

IUPAC Name

[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;

Molecular Weight

734.904g/mol

Molecular Formula

C52H48P2;

Canonical SMILES

CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C;

InChI

InChI=1S/C52H48P2/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46/h9-32H,1-8H3;

InChI Key

MXGXXBYVDMVJAO-UHFFFAOYSA-N;

Application

Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.

Ligand used in the enantioselective fluorination of oxindoles.

Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.

Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.

Asymmetric hydroboration of unsaturated imines.

Complexity

999

Covalently-Bonded Unit Count

1

Exact Mass

734.323g/mol

Heavy Atom Count

54

Monoisotopic Mass

734.323g/mol

Rotatable Bond Count

7

Topological Polar Surface Area

0A^2

MSDS

COA

Spec Sheet