Bromotris(triphenylphosphine)rhodium

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Catalog Number
ACM14973898
Product Name
Bromotris(triphenylphosphine)rhodium
Structure
Structure
CAS
14973-89-8
Category
Rhodium series of catalysts
Synonyms
bromide; Bromotris(triphenylphosphine)rhodium; EINECS 239-050-5; Bromotris(triphenylphosphine)rhodium(I); Jsp002843; phosphine, triphenyl-, bromide, rhodium salt(3:1); RL01906; AC1Q1R7U; triphenylphosphane;
IUPAC Name
rhodium;triphenylphosphane;bromide;
Molecular Weight
969.685g/mol
Molecular Formula
C54H45BrP3Rh-;
Canonical SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Br-].[Rh];
InChI
InChI=1S/3C18H15P.BrH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1;
InChI Key
HVQBRJSQQWBTDF-UHFFFAOYSA-M;
Application
Rhodium-catalyzed regio- and stereoselective addition of diphenylphosphine oxide to alkynes.

Rhodium- catalyzed hydrophosphinylation.
Complexity
202
Covalently-Bonded Unit Count
5
EC Number
239-050-5
Exact Mass
968.097g/mol
Formal Charge
-1
H-Bond Acceptor
1
Heavy Atom Count
59
Monoisotopic Mass
968.097g/mol
Rotatable Bond Count
9
Topological Polar Surface Area
0A^2
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