Catalog Number
ACM1070663783
Category
Organic Phosphine Compounds
Synonyms
C35H53O2P; dicyclohexyl-(2',4',6'-triisopropyl-3,6-dimethoxy-biphenyl-2-yl)-phosphane; BrettPhos; 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl; ZINC43220891; ST24046493; 2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISOPROPYL-3,6-DIMETHOXYBIPHENYL; AS-19342; 2-(Dicyclohexylphosphino)3,6-dimethoxy-2 inverted exclamation marka,4 inverted exclamation marka,6 inverted exclamation marka-triisopropyl-1,1 inverted exclamation marka-biphenyl; 2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl;
IUPAC Name
dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;
Molecular Weight
536.781g/mol
Molecular Formula
C35H53O2P;
Canonical SMILES
CC(C)C1=CC(=C(C(=C1)C(C)C)C2=C(C=CC(=C2P(C3CCCCC3)C4CCCCC4)OC)OC)C(C)C;
InChI
InChI=1S/C35H53O2P/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28/h19-25,27-28H,9-18H2,1-8H3;
InChI Key
WDVGNXKCFBOKDF-UHFFFAOYSA-N;
Application
Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.
Covalently-Bonded Unit Count
1
Monoisotopic Mass
536.378g/mol
Topological Polar Surface Area
18.5A^2
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