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Catalog Number
ACM84127048
Product Name
Bis(4-methoxyphenyl)phosphine
Structure
CAS
84127-04-8
Synonyms
DTXSID90463443; 2928AC; 4CH-016750; ACMC-20aeev; TC-158350; KS-00000QED; ZINC100025504; ST2412684; CTK8C3052; FWKICRREDMVWRF-UHFFFAOYSA-N;
IUPAC Name
bis(4-methoxyphenyl)phosphane;
Molecular Formula
C14H15O2P;
Molecular Weight
246.246g/mol
Rotatable Bond Count
4
Exact Mass
246.081g/mol
Monoisotopic Mass
246.081g/mol
Topological Polar Surface Area
18.5A^2
Heavy Atom Count
17
Complexity
184
Covalently-Bonded Unit
1
SMILES
COC1=CC=C(C=C1)PC2=CC=C(C=C2)OC;
InChI
InChI=1S/C14H15O2P/c1-15-11-3-7-13(8-4-11)17-14-9-5-12(16-2)6-10-14/h3-10,17H,1-2H3;
InChI Key
FWKICRREDMVWRF-UHFFFAOYSA-N;
H-Bond Acceptor
2
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1 The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation.

Werlé C1, Goddard R1, Fürstner A2.

Angew Chem Int Ed Engl. 2015 Dec 14;54(51):15452-6. doi: 10.1002/anie.201506902. Epub 2015 Nov 4.

The dirhodium carbene derived from bis(4-methoxyphenyl)diazomethane and [Rh(tpa)4 ]⋅CH2 Cl2 (tpa=triphenylacetate) was characterized by UV, IR, and NMR spectroscopy, HRMS, as well as by X-ray diffraction. The isolated complex exhibits prototypical rhodium carbene reactivity in that it cyclopropanates 4-methoxystyrene at low temperature. Experimental structural information on this important type of ... Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA