Nakajima Y1, Sato K2, Shimada S3.
Chem Rec. 2016 Oct;16(5):2379-2387. doi: 10.1002/tcr.201600056. Epub 2016 Aug 8.In this account, our studies on nickel-catalyzed hydrosilylation reactions are described. A series of (salicylaldiminato)methylnickel complexes efficiently catalyze alkene hydrosilylation under ambient reaction conditions. Commercially available Ni(II) salts, Ni(acac)2 (acac = acetylacetonato) and its derivatives bis(hexafluoroacetylacetonato)nickel(II) and bis (2,2,6,6-tetramethyl-3,5-heptanediona ... Read More