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Catalog Number
ACM2551839
Product Name
Allyltrimethoxysilane
Structure
CAS
2551-83-9
Synonyms
Silane,trimethoxy-2-propenyl-;trimethoxy-2-propenyl-silan;trimethoxy-2-propenyl-Silane;TRIMETHOXYALLYLSILANE;ALLYLTRIMETHOXYSILANE;Allyltrimethoxysilane, 97+%;3-(Trimethoxysilyl)-1-propene;Allytrimethoxysilane
Molecular Formula
C6H14O3Si
Molecular Weight
162.26
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1 Enantioselective Ag-Catalyzed Allylation of Aldimines.

Naodovic M1, Wadamoto M, Yamamoto H.

European J Org Chem. 2009 Aug 26;2009(30):5129-5131.

A highly enantioselective synthesis of homoallylic amines, using allyltrimethoxysilane under Ag(I) catalytic conditions, has been developed. Among the chiral ligands investigated, a remarkable difference in the resulting Ag(I) complexes was observed. Under mild conditions and low catalyst loadings, homoallylamines were produced in high ee values (up to 80%) and good yields. The methodology can be further extended to a diastere- and enantioselective crotylation of aldimines.

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA