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Home > Product > Organic Building Blocks > Organic Silicon Compounds > Alkyl Silane > 2-(Trimethylsilyl)phenyltrifluoromethanesulfonate

2-(Trimethylsilyl)phenyltrifluoromethanesulfonate

Catalog Number
ACM88284484
Product Name
2-(Trimethylsilyl)phenyltrifluoromethanesulfonate
Structure
CAS Number
88284-48-4
IUPAC Name
(2-trimethylsilylphenyl)trifluoromethanesulfonate
Synonyms
(2-trimethylsilylphenyl) trifluoromethanesulfonate;
Category
Acyloxy hydrocarbyl silane
Molecular Weight
298.35
Exact Mass
298.03100
Molecular Formula
C10H13F3O3SSi
Boiling Point
70ºC2 mm Hg(lit.)
Flash Point
205 °F
Density
1.229 g/mL at 25ºC(lit.)
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)C1=CC=CC=C1OS(=O)(=O)C(F)(F)F
InChIKey
XBHPFCIWRHJDCP-UHFFFAOYSA-N
Safty Description
26-27-36/37/39-45
Hazard Statements
C: Corrosive;
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11,3-Dipolar cycloaddition of sugar azides with benzyne: a novel synthesis of 1,2,3-benzotriazolyl glycoconjugates.

Subba Reddy BV1, Praneeth K, Yadav JS.

Carbohydr Res. 2011 Jun 1;346(8):995-8. doi: 10.1016/j.carres.2010.12.015. Epub 2010 Dec 22.

Glycosyl azides undergo smooth 1,3-dipolar cycloaddition with benzyne generated in situ from 2-(trimethylsilyl)phenyltrifluoromethanesulfonate and cesium fluoride under mild conditions to furnish 1,2,3-benzotriazole-linked glycoconjugates in excellent yields and with high stereoselectivity. This method provides a novel class of benzotriazole linked glycoconjugates in a single-step reaction. This is the first example of a fluoride- triggered 1,3-dipolar cycloaddition of benzyne with glycosyl azides.Copyright © 2010 Elsevier Ltd. All rights reserved.

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA