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Phenyldimethylsilane

Catalog Number
ACM766778
Product Name
Phenyldimethylsilane
Structure
CAS Number
766-77-8
EC Number
212-170-5
IUPAC Name
dimethyl(phenyl)silicon
Synonyms
Dimethylphenyl silane, Phenyldimethylsilane, Silane, dimethylphenyl-, DIMETHYLPHENYLSILANE, EINECS 212-170-5, CID6327656, TL8006673, 766-77-8
Category
Organic hydrogen silane
Molecular Weight
136.27
Exact Mass
136.07100
Molecular Formula
C8H12Si
Boiling Point
156ºC(744 torr)
Melting Point
323-329ºC(lit.)
Flash Point
95 °F
Density
0.88
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)C1=CC=CC=C1
InChIKey
OIKHZBFJHONJJB-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Safty Description
S23-S24/25
Hazard Statements
Xi
WGK Germany
1
Packing Group
III
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1Synthesis of the A-B subunit of angelmicin B.

Lambert WT1, Roush WR.

Org Lett. 2005 Nov 24;7(24):5501-4.

[reaction: see text] An efficient synthesis of the tricyclic A-B subunit 2 of angelmicin B is described. A formal three-component coupling of aldehydes 4 and 6 with gamma-silylallylborane 7 was employed to assemble the tetrahydrofuranyl core of 2, a strategy highlighted by the stereoselective [3 + 2] annulation of allylsilanes 5a/5b with aldehyde 4. The efficiency of the [3 + 2] annulation was greatly improved by using the allylic benzhydryldimethylsilane 5b compared to the allylic phenyldimethylsilane 5a.

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Email:
Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA