Yoshioka H1, Suzuki M, Mugisawa M, Naitoh N, Sawada H.
J Colloid Interface Sci. 2007 Apr 1;308(1):4-10. Epub 2006 Dec 16.Fluoroalkanoyl peroxide reacted with 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane (TTRV-Si) to afford fluoroalkyl end-capped oligomers containing some unreacted vinyl segments under very mild conditions. Fluoroalkyl end-capped cyclosiloxane oligomers containing some vinyl segments thus obtained reacted with N,N-dimethylacrylamide and fluoroalkanoyl peroxide to afford new fluorinated dendrimer-type block copolymers in good isolated yield. Read More