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Diisopropylsilane

Catalog Number
ACM18209660
Product Name
Diisopropylsilane
Structure
CAS Number
18209-66-0
IUPAC Name
di(propan-2-yl)silicon
Synonyms
DIISOPROPYLSILANE, 18209-66-0, AKOS006277132, AKOS015909123, KB-49963, FT-0694956, I14-33834
Category
Organic hydrogen silane
Molecular Weight
116.28
Exact Mass
114.08600
Molecular Formula
C6H16Si
Purity
95%+
Appearance
Transparent liquid
SMILES
CC(C)[Si]C(C)C
InChIKey
MQUBEBJFHBANKV-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
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1Intramolecular Chain Hydrosilylation of Alkynylphenylsilanes Using a Silyl Cation as a Chain Carrier.

Arii H1, Nakabayashi K2, Mochida K3, Kawashima T4.

Molecules. 2016 Aug 1;21(8). pii: E999. doi: 10.3390/molecules21080999.

Diorganyl[2-(trimethylsilylethynyl)phenyl]silanes 1a-c and methyl-substituted phenylsilanes 1d and 1e were treated with a small amount of trityl tetrakis(pentafluorophenyl)borate (TPFPB) as an initiator in benzene to afford the corresponding benzosiloles (2a-e) in moderate to good yields. However, no reaction was observed for the reaction using [2-(1-hexynyl)phenyl]diisopropylsilane lf. The methyl substituent was tolerated under the reaction conditions and increased the yield of the corresponding benzosilole depending on the substitution position. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA