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Home > Products > Material & Chemicals > Micro/NanoElectronics > (Acetylacetonato)(1,5-cyclooctadiene)iridium(I)

Catalog Number
ACM12154846
Product Name
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
Structure
CAS
12154-84-6
Symbol
GHS07
Synonyms
1,5-CYCLOOCTADIENE(ACETYLACETONATO)IRIDIUM (I);(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)IRIDIUM(I);IRIDIUM I PENTANEDIONATE-CYCLO-OCTADIENE COMPLEX;((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o')-iridiu;(1,5-cyclooctadiene)(2,4-pentanedionato)irid
MDL Number
MFCD08273779
IUPAC Name
cyclooctane; (Z)-4-hydroxypent-3-en-2-one; iridium
Molecular Formula
C13H19IrO2
Molecular Weight
399.51
Exact Mass
384.10700
Boiling Point
152ºC at 760 mmHg
Melting Point
145-150ºC (dec.)
Flash Point
30ºC
Appearance
yellow powder
SMILES
C[C-]=CC(=O)C.C1C[CH][CH]CC[CH][CH]1.[Ir]
InChI Key
RBTXDZDKTGRPBP-LWFKIUJUSA-N
H-Bond Donor
1
H-Bond Acceptor
2
Safty Description
26
Hazard Statements
Xi: Irritant;
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1 Efficient Synthesis of Tris-Heteroleptic Iridium(III) Complexes Based on the Zn2+-Promoted Degradation of Tris-Cyclometalated Iridium(III) Complexes and Their Photophysical Properties.

Tamura Y1, Hisamatsu Y1, Kumar S1, Itoh T1, Sato K1, Kuroda R1, Aoki S1.

Inorg Chem. 2016 Dec 30. doi: 10.1021/acs.inorgchem.6b02270. [Epub ahead of print]

We report on the efficient synthesis of tris-heteroleptic iridium (Ir) complexes based on the degradation of tris-cyclometalated Ir complexes (IrL3, L: cyclometalating ligand) in the presence of Brønsted and Lewis acids such as HCl (in 1,4-dioxane), AlCl3, TMSCl, and ZnX2 (X = Br or Cl), which affords the corresponding halogen-bridged Ir dimers (μ-complexes). Tris-cyclometalated Ir complexes contai ... Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA