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Home > Product > Boronic Compounds > Boronic Acids > 2-Methyl-4-methoxyphenylboronic acid

2-Methyl-4-methoxyphenylboronic acid

Catalog Number
ACM208399660
Product Name
2-Methyl-4-methoxyphenylboronic acid
Structure
CAS Number
208399-66-0
IUPAC Name
(4-methoxy-2-methylphenyl)boronic acid
Synonyms
AKOS BRN-0221;4-METHOXY-2-METHYLBENZENEBORONIC ACID;4-METHOXY-2-METHYLPHENYLBORONIC ACID;2-methyl-4-methoxyphenylboronic acid;4-Methoxy-2-methylphebylboronic acid;4-Methoxy-2-Methylphenylboroni;4-Methoxy-2-methylphenylboronic acid ,98%;4-Methoxy-2-Methylp
Molecular Formula
C8H11BO3
Molecular Weight
165.98
Exact Mass
166.08000
Boiling Point
327.1ºC at 760mmHg
Melting Point
169-174ºC(lit.)
Flash Point
151.6ºC
Density
1.14g/cm3
Purity
97%
SMILES
B(C1=C(C=C(C=C1)OC)C)(O)O
InChIKey
AMSQNQJCBXQYEX-UHFFFAOYSA-N
H-Bond Donor
2
H-Bond Acceptor
3
Safty Description
S26-S36
Hazard Statements
Xi: Irritant;
WGK Germany
3
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1Synthesis, conformational stability, and asymmetric transformation of atropisomeric 1,8-bisphenolnaphthalenes.

Ghosn MW1, Wolf C.

J Org Chem. 2011 May 20;76(10):3888-97. doi: 10.1021/jo200309g. Epub 2011 Apr 8.

Highly congested, axially chiral 1,8-bisphenolnaphthalenes have been synthesized in 75% overall yield by palladium-catalyzed Suzuki coupling of 1,8-diiodonaphthalene and 4-methoxy-2-methylphenylboronic acid followed by regioselective formylation and deprotection. The C(2)-symmetric anti-stereoisomers of 1,8-bis(2'-methyl-4'-hydroxy-5'-formylphenyl)naphthalene, 5, and its diimine analogues 9 and 10 were found to be significantly more stable than the corresponding syn-isomer. Read More

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Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA