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Home > Product > Boronic Compounds > Boronic Acids > 1-Naphthylboronic acid

1-Naphthylboronic acid

Catalog Number
ACM13922413
Product Name
1-Naphthylboronic acid
Structure
CAS Number
13922-41-3
Synonyms
NAPHTHALENYL-1-BORONIC ACID;NAPHTHALEN-1-YLBORONIC ACID;NAPHTHALENE-1-BORONIC ACID;RARECHEM AH PB 0125;1-NAPHTHYLBORONIC ACID;1-NAPHTHYLENEBORONIC ACID;1-NAPHTHALENEBORONIC ACID;ALPHA-NAPHTHYLBORIC ACID
Molecular Formula
C10H9BO2
Molecular Weight
171.99
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1Enantioselective synthesis of axially chiral biaryls by the Pd-catalyzed Suzuki-Miyaura reaction: substrate scope and quantum mechanical investigations.

Shen X1, Jones GO, Watson DA, Bhayana B, Buchwald SL.

J Am Chem Soc. 2010 Aug 18;132(32):11278-87. doi: 10.1021/ja104297g.

We report efficient syntheses of axially chiral biaryl amides in yields ranging from 80-92%, and with enantioselectivity in the range 88-94% ee employing an asymmetric Suzuki-Miyaura process with Pd(OAc)(2) and KenPhos as ligand. These studies demonstrate that electron-rich and electron-deficient o-halobenzamides can be efficiently coupled with 2-methyl-1-naphthylboronic acid and 2-ethoxy-1-naphthylboronic acid. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA