1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)

• Catalog Number: ACM104439772-1
• Product Name: 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)
• CAS: 104439-77-2
• Category: Ruthenium series catalysts
• Synonyms: Shvo's catalyst
• Molecular Weight: 1084.1
• Molecular Formula: C62H41O6Ru2
• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)C2=C(C(=O)C(=C2C3=CC=CC=C3)C4=CC=CC=C4)C5=CC=CC=C5.C1=CC=C(C=C1)[C]2[C]([C]([C]([C]2C3=CC=CC=C3)O)C4=CC=CC=C4)C5=CC=CC=C5.[Ru].[Ru]
• InChI: InChI=1S/C29H21O.C29H20O.4CO.2Ru/c2*30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;4*1-2;/h1-20,30H;1-20H
• InChI Key: LYADOKFHMFDLJK-UHFFFAOYSA-N
• Melting Point: 223-227 °C
• Appearance: Powder
• Application: In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates into chiral acetates.; ; Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.; ; Conversion of secondary amines to primary amines in the presence of ammonia.; ; Co-catalyt for aerobic lactonization of diols.
• Exact Mass: 1087.10008
• Hydrogen Bond Acceptor Count: 6
• Hydrogen Bond Donor Count: 1
• Monoisotopic Mass: 1085.098995
• Rotatable Bond Count: 8
• Topological Polar Surface Area: 41.3 Ų

Custom Reviews

January 20, 2023

Work well in preparing composite catalyst

The combination of 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) and lipase can be used for asymmetric conversion of ketones and enolacetates.