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Home > Products > Organic Building Blocks > Organic Phosphine Compounds > 1,4-Bis(dicyclohexylphosphino)butane

Catalog Number
ACM65038360
Product Name
1,4-Bis(dicyclohexylphosphino)butane
Structure
CAS
65038-36-0
Synonyms
MFCD00239357; SCHEMBL220818; Phosphine, 1,4-butanediylbis[dicyclohexyl-; TC-172180; AN-38662; 65038-36-0; dicyclohexyl(4-dicyclohexylphosphanylbutyl)phosphane; Dicyclohexyl[4-(dicyclohexylphosphino)butyl]phosphine #; AKOS025295593; I14-1710;
IUPAC Name
dicyclohexyl(4-dicyclohexylphosphanylbutyl)phosphane;
Molecular Formula
C28H52P2;
Molecular Weight
450.672g/mol
Rotatable Bond Count
9
Exact Mass
450.354g/mol
Monoisotopic Mass
450.354g/mol
Topological Polar Surface Area
0A^2
Heavy Atom Count
30
Complexity
362
Covalently-Bonded Unit
1
SMILES
C1CCC(CC1)P(CCCCP(C2CCCCC2)C3CCCCC3)C4CCCCC4;
InChI
InChI=1S/C28H52P2/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h25-28H,1-24H2;
InChI Key
WNZGLXFLSFWPMP-UHFFFAOYSA-N;
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1 Evaluation of C4 diphosphine ligands in rhodium catalysed methanol carbonylation under a syngas atmosphere: synthesis, structure, stability and reactivity of rhodium(I) carbonyl and rhodium(III) acetyl intermediates.

Lamb G1, Clarke M, Slawin AM, Williams B, Key L.

Dalton Trans. 2007 Dec 21;(47):5582-9. Epub 2007 Oct 10.

The carbonylation of methanol to acetic acid is a hugely important catalytic process, and there are considerable cost and environmental advantages if a process could be designed that was tolerant of hydrogen impurities in the CO feed gas, while eliminating by-products such as propionic acid and acetaldehyde altogether. This paper reports on an investigation into the application of rhodium complexes ... Read More

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Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA