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1,3,5-TRIMETHYLBORAZINE;Borazine,1,3,5-trimethyl-;N,N,N-Trimethylborazine;Trimethylborazine;N,N,N"1,3,5-Trimethyl-1,3,5-triaza-2,4,6-triboracyclohexane;NSC 10221;1,3,5-TriMethyl-1,3,5,2,4,6-triazatriborinane
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Synthesis of B-Trisubstituted Borazines from 1,3,5-Trimethylborazine

Yasunori Yamamoto, et al. Journal of Organometallic Chemistry, 2006, 691(23), 4909-4917.

Hydroboration of terminal and internal alkenes with N,N',N''-trimethylborazine (1,3,5-Trimethylborazine) at 50°C in the presence of rhodium(I) catalyst. The prepared borazine can be used as the precursor of borazine-based polymers and boron nitride ceramics or as the core skeleton of electroluminescent devices.
Hydroboration of typical alkenes with N-trimethylborazine
· A glass tube charged with N,N',N''-trimethylborazine (0.5 mmol), alkene (3 mmol), [RhCl(coe)2]2 (0.0075 mmol), t-Bu3P (0.033 mmol, P/Rh = 2.1) in toluene (0.5 ml) was sealed under argon atmosphere. The resulting mixture was stirred at 50 C for 24 h. The product was isolated by Kugelrohr distillation.
· The hydroboration of representative alkenes with N,N',N''-trimethylborazine (3a) in the presence of the [RhCl(coe)2]2/4t-Bu3P catalyst is shown in Table 4. The reactions of terminal and internal alkenes smoothly took place under the optimized conditions to selectively provide B-(n-alkyl)borazines (6b-e) in high yields (entries 1-10).

What is the molecular formula of 1,3,5-Trimethylborazine?

The molecular formula of 1,3,5-Trimethylborazine is C3H9B3N3.

What are the synonyms for 1,3,5-Trimethylborazine?

The synonyms for 1,3,5-Trimethylborazine are Borazine, 1,3,5-trimethyl- and N,N',N''-Trimethylborazine.

What is the molecular weight of 1,3,5-Trimethylborazine?

The molecular weight of 1,3,5-Trimethylborazine is 119.6 g/mol.

What is the InChI of 1,3,5-Trimethylborazine?

The InChI of 1,3,5-Trimethylborazine is InChI=1S/C3H9B3N3/c1-7-4-8(2)6-9(3)5-7/h1-3H3.

What is the InChIKey of 1,3,5-Trimethylborazine?

The InChIKey of 1,3,5-Trimethylborazine is MAAKAMQHYNNJEP-UHFFFAOYSA-N.

What is the canonical SMILES representation of 1,3,5-Trimethylborazine?

The canonical SMILES representation of 1,3,5-Trimethylborazine is [B]1N([B]N([B]N1C)C)C.

What is the CAS number of 1,3,5-Trimethylborazine?

The CAS number of 1,3,5-Trimethylborazine is 1004-35-9.

What is the European Community (EC) Number of 1,3,5-Trimethylborazine?

The European Community (EC) Number of 1,3,5-Trimethylborazine is 690-848-3.

What is the UNII of 1,3,5-Trimethylborazine?

The UNII of 1,3,5-Trimethylborazine is 8TA5Q6XG3S.

What is the physical description of 1,3,5-Trimethylborazine?

1,3,5-Trimethylborazine is described as a clear colorless liquid with a mild odor that fumes in air.

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