(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh

• Catalog Number: ACM205064104
• Product Name: (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh
• CAS: 205064-10-4
• Category: Rhodium series of catalysts
• Synonyms: (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)Rh(I)tetrafluoroborate; (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane; MFCD01862467; 205064-10-4; AC1MC1E8
• IUPAC Name: cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane;rhodium;tetrafluoroborate
• Molecular Weight: 604.263g/mol
• Molecular Formula: C26H40BF4P2Rh-
• Canonical SMILES: [B-](F)(F)(F)F.CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C.C1CC=CCCC=C1.[Rh]
• InChI: InChI=1S/C18H28P2.C8H12.BF4.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/t13-,14-,15-,16-;;;/m0.../s1
• InChI Key: ZUMNNKGIZSDCBZ-KXSXXMSISA-N
• Application: The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.; ; Forms superior catalysts for asymmetric reductive aminations.; ; Catalyst used for the asymmetric hydrogenation of enol phosphonates.; ; A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.; ; Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.; ; Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.; ; Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.; ; Palladium catalyzed asymmetric phosphination.
• Complexity: 369
• Covalently-Bonded Unit Count: 4
• Defined Atom Stereocenter Count: 4
• Exact Mass: 604.169g/mol
• Formal Charge: -1
• H-Bond Acceptor: 5
• Heavy Atom Count: 34
• Monoisotopic Mass: 604.169g/mol
• Rotatable Bond Count: 2
• Topological Polar Surface Area: 0A^2
• Undefined Bond Stereocenter Count: 2

Custom Reviews

January 20, 2023

Work great in drug synthesis

(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (98+% (S,S)-Me-DUPHOS-Rh) catalyzes the conversion of various ketones into corresponding chiral amines with high enantioselectivity, which is used to synthesize pharmaceutical intermediates.

Custom Q&A

What is molecular formula of (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (98+% (S,S)-Me-DUPHOS-Rh)?

C26H40BF4P2Rh

What is the heavy atom count of (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (98+% (S,S)-Me-DUPHOS-Rh)?

34

What is exact mass of (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (98+% (S,S)-Me-DUPHOS-Rh)?

604.16894

What is the sensitivity of (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (98+% (S,S)-Me-DUPHOS-Rh)?

Air sensitive

What is the CAS number of (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (98+% (S,S)-Me-DUPHOS-Rh)?

205064-10-4