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Vinyl methacrylate | CAS Number: 4245-37-8

Catalog Number
ACM4245378
Product Name
Vinyl methacrylate
Structure
CAS Number
4245-37-8
Synonyms
METHACRYLIC ACID VINYL ESTER;VINYL METHACRYLATE;VINYL METHACRYLATE, 98%, STAB. WITH 200PPM 4-METHOXYPHENOL;METHACRYLIC ACID VINYL ESTER (STABILIZED WITH MEHQ) 98+%;Vinylmethacrylate,98%;2-PROPENOICACID,2-METHYL-,ETHENYLESTER;METHACRYLIC ACID VINYL ESTER(S
Molecular Weight
112.13
Molecular Formula
C6H8O2
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1Robust Cross-Linked Stereocomplexes and C60 Inclusion Complexes of Vinyl-Functionalized Stereoregular Polymers Derived from Chemo/Stereoselective Coordination Polymerization.

Vidal F1, Falivene L2, Caporaso L3, Cavallo L2, Chen EY1.

J Am Chem Soc. 2016 Aug 3;138(30):9533-47. doi: 10.1021/jacs.6b04064. Epub 2016 Jul 19.

The successful synthesis of highly syndiotactic polar vinyl polymers bearing the reactive pendant vinyl group on each repeat unit, which is enabled by perfectly chemoselective and highly syndiospecific coordination polymerization of divinyl polar monomers developed through this work, has allowed the construction of robust cross-linked supramolecular stereocomplexes and C60 inclusion complexes. The metal-mediated coordination polymerization of three representative polar divinyl monomers, including vinyl methacrylate (VMA), allyl methacrylate (AMA), and N,N-diallyl acrylamide (DAA) by Cs-ligated zirconocenium ester enolate catalysts under ambient conditions exhibits complete chemoselectivity and high stereoselectivity, thus producing the corresponding vinyl-functionalized polymers with high (92% rr) to quantitative (>99% rr) syndiotacticity. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA