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Vanadium oxytrifluoride | CAS Number: 13709-31-4

Catalog Number
ACM13709314
Product Name
Vanadium oxytrifluoride
Structure
CAS Number
13709-31-4
Synonyms
Vanadium, trifluorooxo-;VOF3;VANADIUM OXYFLUORIDE;VANADIUM OXYTRIFLUORIDE;VANADYL (V) FLUORIDE;VANADIUM(V) OXYTRIFLUORIDE;VANADIUM (V) TRIFLUORIDE OXIDE;trifluorooxovanadium
Molecular Weight
123.94
Molecular Formula
F3OV
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1Synthesis of tylocrebrine and related phenanthroindolizidines by VOF3-mediated oxidative aryl-alkene coupling.

Niphakis MJ1, Georg GI.

Org Lett. 2011 Jan 21;13(2):196-9. doi: 10.1021/ol1023954. Epub 2010 Dec 14.

A highly convergent strategy to prepare phenanthroindolizidines is reported involving three consecutive C-C coupling reactions. This sequence features a novel VOF(3)-mediated aryl-alkene coupling in the final step, which enables regioselective preparation of C5-substituted phenanthroindolizidines for the first time. This strategy has been applied to the synthesis of eight natural and unnatural members in this class to investigate the scope of this chemistry and to explore structure-activity relationships.

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA