Werner M1, Heil A1, Rothermel N1, Breitzke H1, Groszewicz PB1, Thankamony AS1, Gutmann T2, Buntkowsky G3.
Solid State Nucl Magn Reson. 2015 Nov;72:73-8. doi: 10.1016/j.ssnmr.2015.09.008. Epub 2015 Sep 18.The successful synthesis and solid state NMR characterization of silica-based organic-inorganic hybrid materials is presented. For this, collagen-like peptides are immobilized on carboxylate functionalized mesoporous silica (COOH/SiOx) materials. A pre-activation of the silica material with TSTU (O-(N-Succinimidyl)-N,N,N',N'-tetramethyluronium tetrafluoroborate) is performed to enable a covalent binding of the peptides to the linker. Read More