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Home > Product > Precious Metal Catalyst > Tris(triphenylphosphine)rhodium(I)carbonyl hydride

Tris(triphenylphosphine)rhodium(I)carbonyl hydride | CAS Number: 17185-29-4

Catalog Number
ACM17185294
Product Name
Tris(triphenylphosphine)rhodium(I)carbonyl hydride
Structure
CAS Number
17185-29-4
UN Number
UN 2811 6.1 / PGIII
MDL Number
MFCD00151644
Synonyms
Carbonyltris(triphenylphosphine)rhodium(I) hydride
Molecular Weight
918.78
Molecular Formula
RhH(CO)(PPh3)3
Melting Point
150 °C (dec.)(lit.)
Purity
Rh ≥11.2%
Appearance
yellow crystals
Symbol
GHS06
Safty Description
Danger
Hazard Statements
H301 + H311 + H331
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1Facile synthesis of rhodium and iridium complexes bearing a [PEP]-type ligand (E = Ge or Sn) via E-C bond cleavage.

Kameo H1, Ishii S, Nakazawa H.

Dalton Trans. 2012 Oct 7;41(37):11386-92. doi: 10.1039/c2dt30996c. Epub 2012 Aug 13.

Rhodium and iridium complexes bearing a tridentate [PEP] type ligand ([PEP] = {o-(Ph(2)P)C(6)H(4)}(2)E(Me); E = Ge or Sn) were synthesized through the phosphine exchange reaction accompanied by selective E-C bond cleavage. The ligand precursors {o-(Ph(2)P)C(6)H(4)}(2)EMe(2) (E = Ge or Sn) were readily obtained in excellent yields by treating {o-(Ph(2)P)C(6)H(4)}(2)Li with 0.5 equivalents of Me(2)ECl(2). Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA