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Home > Product > Precious Metal Catalyst > Tris(ethylenediamine)rhodium(III)chloride

Tris(ethylenediamine)rhodium(III)chloride | CAS Number: 14023-02-0

Catalog Number
ACM14023020
Product Name
Tris(ethylenediamine)rhodium(III)chloride
Structure
CAS Number
14023-02-0
MDL Number
MFCD00149661
Synonyms
Tris(ethylenediamine)rhodium(III) trichloride
Molecular Weight
389.56
Molecular Formula
C6H24Cl3N6Rh
Boiling Point
119.7 °C at 760 mmHg
Melting Point
>300 °C
Density
g/cm3
Purity
Rh 23%
Appearance
white powder
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H302-H315-H319-H335
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1Where does the Raman optical activity of [Rh(en)3](3+) come from? Insight from a combined experimental and theoretical approach.

Humbert-Droz M1, Oulevey P, Lawson Daku LM, Luber S, Hagemann H, Bürgi T.

Phys Chem Chem Phys. 2014 Nov 14;16(42):23260-73. doi: 10.1039/c4cp02145b.

Backscattered Raman optical activity (ROA) spectra are measured for Δ- and Λ-tris-(ethylenediamine)rhodium(III) chloride in aqueous solution. In addition, the spectra of the four possible conformers in the Λ configuration are investigated by ab initio calculations. The Λ(δδδ) conformer is in best agreement with experimental spectra and examined in more details. The two most stable conformers according to the calculations are not compatible with the experimental ROA spectrum. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA