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Home > Product > Material & Chemicals > Micro/NanoElectronics > [Tris(dimethylphenylphosphine)](2,5-norbornadiene)rhodium(i)hexafluorophosphate

[Tris(dimethylphenylphosphine)](2,5-norbornadiene)rhodium(i)hexafluorophosphate | CAS Number: 32761-50-5

Catalog Number
ACM32761505
Product Name
[Tris(dimethylphenylphosphine)](2,5-norbornadiene)rhodium(i)hexafluorophosphate
Structure
CAS Number
32761-50-5
MDL Number
MFCD02091681
Synonyms
[TRIS(DIMETHYLPHENYLPHOSPHINE)](2,5-NORBORNADIENE)RHODIUM(I) HEXAFLUOROPHOSPHATE;(tris(dimethylphenylphosphine))(2,5-norbornadiene;(TRIS(DIMETHYLPHENYLPHOSPHINE))(2,5-NORB ORNADIENE)RHODIUM(I)PF6, 97%;(dimethylphenylphosphine)(norbornadiene)rhodium fluoro
Molecular Weight
754.45
Molecular Formula
C31H41F6P4Rh 4*
Melting Point
158-161 °C(lit.)
Purity
0.97
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H315-H319-H335
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1Solid-state phosphorus-31 NMR spectroscopy of a multiple-spin system: an investigation of a rhodium-triphosphine complex.

Bernard GM1, Feindel KW, Wasylishen RE, Cameron TS.

Phys Chem Chem Phys. 2008 Sep 28;10(36):5552-63. doi: 10.1039/b803596b. Epub 2008 Jul 21.

Phosphorus-31 NMR spectra of solid [tris(dimethylphenylphosphine)](2,5-norbornadiene) rhodium(I) hexafluorophosphate have been acquired at several applied magnetic field strengths. The phosphorus nuclei of the three phosphine ligands are spin-spin coupled to each other and to 103Rh, resulting in complex NMR spectra; however, the three phosphorus chemical shift (CS) tensors were determined through the analysis of NMR spectra of slow magic angle spinning and stationary samples. Read More

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Tel:1-201-478-8534
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