Bernard GM1, Feindel KW, Wasylishen RE, Cameron TS.
Phys Chem Chem Phys. 2008 Sep 28;10(36):5552-63. doi: 10.1039/b803596b. Epub 2008 Jul 21.Phosphorus-31 NMR spectra of solid [tris(dimethylphenylphosphine)](2,5-norbornadiene) rhodium(I) hexafluorophosphate have been acquired at several applied magnetic field strengths. The phosphorus nuclei of the three phosphine ligands are spin-spin coupled to each other and to 103Rh, resulting in complex NMR spectra; however, the three phosphorus chemical shift (CS) tensors were determined through the analysis of NMR spectra of slow magic angle spinning and stationary samples. Read More