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Home > Product > Material & Chemicals > Micro/NanoElectronics > Tris(cyclopentadienyl)thulium

Tris(cyclopentadienyl)thulium | CAS Number: 1272-26-0

Catalog Number
ACM1272260
Product Name
Tris(cyclopentadienyl)thulium
Structure
CAS Number
1272-26-0
EC Number
215-052-1
IUPAC Name
cyclopenta-1,3-diene; thulium(3+)
Synonyms
Thulium, tris(eta(5)-2,4-cyclopentadien-1-yl)-;TRIS(CYCLOPENTADIENYL)THULIUM;tris(eta5-2,4-cyclopentadien-1-yl)thulium;Tris(cyclopentadienyl)thulium (III);TRIS(CYCLOPENTADIENYL)THULIUM, 99.9%;TRIS(CYCLOPENTADIENYL)THULIUM (99.9%-TM) (REO);99.9%-tm)(reo);T
Molecular Weight
364.21
Exact Mass
364.05200
Molecular Formula
C15H15Tm 15*
Boiling Point
41.5ºC at 760 mmHg
Melting Point
248-249ºC (dec.)(lit.)
Purity
96%
SMILES
C1C=CC=[C-]1.C1C=CC=[C-]1.C1C=CC=[C-]1.[Tm+3]
InChIKey
MWWSVGXLSBSLQO-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
3
Safty Description
43-7/8
Hazard Statements
F: Flammable;
Packing Group
III
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1Synthesis of a new stable, neutral organothulium(II) complex by reduction of a thulium(III) precursor.

Jaroschik F1, Nief F, Ricard L.

Chem Commun (Camb). 2006 Jan 28;(4):426-8.

The new stable, neutral Tm(II) complex (Cp(ttt))2Tm [Cp(ttt) = 1,2,4-tris(tert-butyl)cyclopentadienyl] can be obtained either by direct reaction of NaCp(ttt) with TmI2 or by reduction of (Cp(ttt))2TmI in non-polar solvents; this latter route may prove itself useful for the isolation of other neutral non-classical low-valent organolanthanide species.

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA