Amberger HD1, Reddmann H2, Mueller TJ3, Evans WJ3.
Spectrochim Acta A Mol Biomol Spectrosc. 2014 Oct 15;131:577-86. doi: 10.1016/j.saa.2014.04.068. Epub 2014 Apr 24.The polarized Raman spectra of an oriented La(η(5)-C5Me5)3 (1) single crystal (where the principal axes of the two molecules per unit cell are uniformly oriented) as well as the mid (ca. 90K) and far infrared spectra of pellets have been recorded. Applying the selection rules of C3h symmetry to the spectra obtained, the irreducible representations (irreps) of numerous lines/bands of intra-ligand character were derived. Read More