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Home > Product > Precious Metal Catalyst > Tris(acetonitrile)cyclopentadienylruthenium(II)hexafluorophosphate

Tris(acetonitrile)cyclopentadienylruthenium(II)hexafluorophosphate | CAS Number: 80049-61-2

Catalog Number
ACM80049612
Product Name
Tris(acetonitrile)cyclopentadienylruthenium(II)hexafluorophosphate
Structure
CAS Number
80049-61-2
MDL Number
MFCD02684569
Synonyms
(Cyclopentadienyltris(acetonitrile)ruthenium hexafluorophosphate
Molecular Weight
434.28
Molecular Formula
C11H14F6N3PRu
Purity
0.98
Appearance
yellow to orange powder
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H315-H319-H335
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1Formation of vinyl halides via a ruthenium-catalyzed three-component coupling.

Trost BM1, Pinkerton AB.

J Am Chem Soc. 2002 Jun 26;124(25):7376-89.

The ruthenium-catalyzed three-component coupling of an alkyne, an enone, and halide ion to form E- or Z-vinyl halides has been investigated. Through systematic optimization experiments, the conditions effecting the olefin selectivity were examined. In general, more polar solvents such as DMF favored the formation of the E-isomer, and less polar solvents such as acetone favored formation of the Z-isomer. Read More

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Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA