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Home > Product > Heterocyclic Organic Compounds > Triphenylborane-sodium hydroxide adduct

Triphenylborane-sodium hydroxide adduct | CAS Number: 12113-07-4

Catalog Number
ACM12113074
Product Name
Triphenylborane-sodium hydroxide adduct
Structure
CAS Number
12113-07-4
IUPAC Name
sodium hydroxy(triphenyl)boranuide
Synonyms
TRIPHENYLBORANE-SODIUM HYDROXIDE ADDUCT;TRIPHENYL BORON-SODIUM HYDROXIDE ADDUCT;TRIPHENYL BORON-SODIUM HYDROXYDE ADDUCT;sodium,(beta-4)-borate(1-hydroxytriphenyl-;Triphenyl boron-sodium hydroxyde adduct (7-9% in water);sodium hydroxytriphenylborate(1-);TR
Molecular Weight
282.12
Exact Mass
282.11900
Molecular Formula
C18H16BNaO
Purity
96%
InChIKey
SUZMSMLUONFLDA-UHFFFAOYSA-N
H-Bond Donor
1
H-Bond Acceptor
2
Safty Description
26-36/37/39-45
Hazard Statements
C: Corrosive;
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1Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects.

Rafiee M1, Miles KC1, Stahl SS1.

J Am Chem Soc. 2015 Nov 25;137(46):14751-7. doi: 10.1021/jacs.5b09672. Epub 2015 Nov 13.

Bicyclic nitroxyl derivatives, such as 2-azaadamantane N-oxyl (AZADO) and 9-azabicyclo[3.3.1]nonane N-oxyl (ABNO), have emerged as highly effective alternatives to TEMPO-based catalysts for selective oxidation reactions (TEMPO = 2,2,6,6-tetramethyl-1-piperidine N-oxyl). Their efficacy is widely attributed to their smaller steric profile; however, electrocatalysis studies described herein show that the catalytic activity of nitroxyls is more strongly affected by the nitroxyl/oxoammonium redox potential than by steric effects. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA