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Triphenylborane | CAS Number: 960-71-4

Catalog Number
ACM960714
Product Name
Triphenylborane
Structure
CAS Number
960-71-4
Synonyms
BORON TRIPHENYL;TRIPHENYLBORANE;TRIPHENYLBORINE;TRIPHENYLBORON;borine,triphenyl;Triphenyboron;triphenyl-boran;TRIPHENYLBORON, POWDER, WATER
Molecular Weight
242.12
Molecular Formula
C18H15B
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1Reactivity of a Molecular Magnesium Hydride Featuring a Terminal Magnesium-Hydrogen Bond.

Schnitzler S1, Spaniol TP1, Okuda J1.

Inorg Chem. 2016 Dec 19;55(24):12997-13006. Epub 2016 Dec 1.

The reactivity of the molecular magnesium hydride [Mg(Me3TACD·AliBu3)H] (1) featuring a terminal magnesium-hydrogen bond and an NNNN-type macrocyclic ligand, Me3TACD ((Me3TACD)H = Me3[12]aneN4 = 1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane), can be grouped into protonolysis, oxidation, hydrometalation, (insertion), and hydride ion. Protonolysis of 1 with weak Brønsted acids HX such as terminal acetylenes, amines, silanols, and silanes gave the corresponding derivatives [Mg(Me3TACD·AliBu3)X] (X = C≡CPh, 3; HN(3,5-Me2-C6H3), 4; OSiMe3, 5; OSiPh3, 6; Cl, 7; Br, 8). Read More

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Tel:1-201-478-8534
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