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Home > Product > Metal Organics > Organic Aluminium > Tri-N-octylaluminium

Tri-N-octylaluminium | CAS Number: 1070-00-4

Catalog Number
ACM1070004
Product Name
Tri-N-octylaluminium
Structure
CAS Number
1070-00-4
Synonyms
TNOA;TRIOCTYLALUMINUM;TRI-N-OCTYLALUMINIUM;TRI-N-OCTYL ALUMINUM;trioctyl-aluminu;trioctylaluminium;TRIOCTYLALUMINUM, 25 WT. % SOLUTION IN H EXANES;Aluminum, trioctyl-
Molecular Weight
366.64
Molecular Formula
C24H51Al
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1Insertion, elimination and isomerisation of olefins at alkylaluminium hydride: an experimental and theoretical study.

Weliange NM1, McGuinness DS, Gardiner MG, Patel J.

Dalton Trans. 2015 Sep 14;44(34):15286-96. doi: 10.1039/c5dt00955c.

The insertion, elimination and isomerisation of octenes with di-n-octylaluminium hydride [HAl(Oct)2], tri-n-octylaluminium [Al(Oct)3] and sec-octylaluminium species have been studied as individual steps in a putative aluminium based contrathermodynamic olefin isomerisation process. While elimination of 1-octene from [Al(Oct)3] is energetically unfavourable, the process is driven by high temperature vacuum distillation, leading to very high selectivity to 1-octene (>97%). Read More

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Tel:1-201-478-8534
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