Göransson E1, Boixel J, Fortage J, Jacquemin D, Becker HC, Blart E, Hammarström L, Odobel F.
Inorg Chem. 2012 Nov 5;51(21):11500-12. doi: 10.1021/ic3013552. Epub 2012 Oct 10.In the context of long-range electron transfer for solar energy conversion, we present the synthesis, photophysical, and computational characterization of two new zinc(II) phthalocyanine oligophenylene-ethynylene based donor-bride-acceptor dyads: ZnPc-OPE-AuP(+) and ZnPc-OPE-C(60). A gold(III) porphyrin and a fullerene has been used as electron accepting moieties, and the results have been compared to a previously reported dyad with a tin(IV) dichloride porphyrin as the electron acceptor (Fortage et al. Read More