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Home > Product > Metal Organics > Organic Copper > Thiophenol copper(i)salt

Thiophenol copper(i)salt | CAS Number: 1192-40-1

Catalog Number
ACM1192401
Product Name
Thiophenol copper(i)salt
Structure
CAS Number
1192-40-1
IUPAC Name
benzenethiolate;copper(1+)
Synonyms
phenylthiocopper;Copper(I)thiophenoxide,Phenylthiocopper(I),Thiophenolcopper(I)salt;COPPER(1) THIOPHENOXIDE;PhSCu;Copper(I) thiophenolate >=98.0% (RT)
Molecular Weight
172.714900 [g/mol]
Exact Mass
171.94100
Molecular Formula
C6H5SCu
Melting Point
280ÂșC (dec.)(lit.)
Purity
96%
SMILES
C1=CC=C(C=C1)[S-].[Cu+]
InChIKey
PNNJYDODNCALKD-UHFFFAOYSA-M
H-Bond Donor
0
H-Bond Acceptor
1
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1Ligand-free copper-catalyzed C-S coupling of aryl iodides and thiols.

Sperotto E1, van Klink GP, de Vries JG, van Koten G.

J Org Chem. 2008 Jul 18;73(14):5625-8. doi: 10.1021/jo800491k. Epub 2008 Jun 21.

A protocol for the copper-catalyzed aryl-sulfur bond formation between aryl iodides and thiophenols is reported. The reaction is catalyzed by a low amount (1-2.5 mol %) of readily available and ligand-free copper iodide salt. A variety of diaryl thioethers are synthesized under relatively mild reaction conditions with good chemoselectivity and functional group tolerance.

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Tel:1-201-478-8534
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