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Thallium(i)ethoxide | CAS Number: 20398-06-5

Catalog Number
ACM20398065
Product Name
Thallium(i)ethoxide
Structure
CAS Number
20398-06-5
Synonyms
ethanol,thallium(1+)salt;ethanol,thallium(1++)salt;ethylalcohol,thallium(i);THALLOUS ETHOXIDE;THALLIUM MONOETHYLATE;THALLIUM ETHOXIDE;THALLIUM ETHYLATE (MONO);THALLIUM (I) ETHOXIDE
Molecular Weight
249.44
Molecular Formula
C2H5OTl
Density
3.522 g/mL at 25 °C(lit.)
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1Thallium(I) sandwich, multidecker, and ether complexes stabilized by weakly-coordinating anions: a spectroscopic, structural, and theoretical investigation.

Sarazin Y1, Hughes DL, Kaltsoyannis N, Wright JA, Bochmann M.

J Am Chem Soc. 2007 Jan 31;129(4):881-94.

The reaction of thallium ethoxide with [H(OEt2)2][H2N{B(C6F5)3}2] in diethyl ether afforded [Tl(OEt2)3][H2N{B(C6F5)3}2] (2a), [Tl(OEt2)4][H2N{B(C6F5)3}2] (2b), or [Tl(OEt2)2][H2N{B(C6F5)3}2].CH2Cl2 (2c), depending on the reaction conditions. The dication in the hydrolysis product [Tl4(mu3-OH)2][H2N{B(C6F5)3}2]2.4CH2Cl2 consists of two bridging and two terminal Tl+ ions bound to triply bridging hydroxides. Read More

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