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Home > Product > Metal Organics > Organic Tin > Tetraphenyltin

Tetraphenyltin | CAS Number: 595-90-4

Catalog Number
ACM595904
Product Name
Tetraphenyltin
Structure
CAS Number
595-90-4
Synonyms
TIN TETRAPHENYL;TETRAPHENYLTIN;TETRAPHENYLTIN(IV);TETRAPHENYLSTANNANE;Stannane,tetraphenyl-;tetraphenyl-stannan;Tetraphenylzinn;Tetraphenyltinwhitepowder
Molecular Weight
427.13
Molecular Formula
C24H20Sn
Purity
MP 226-229deg
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1Transition-Metal-Free Cross-Coupling of Aryl Halides with Arylstannanes.

He Q1,2, Wang L1, Liang Y3, Zhang Z1, Wnuk SF3.

J Org Chem. 2016 Oct 7;81(19):9422-9427. Epub 2016 Sep 8.

Transition-metal-free LiCl-promoted cross-coupling reactions of tetraphenyltin, trichlorophenyl-, dichlorodiphenyl-, and chlorotriphenylstannanes with aryl halides in DMF provided access to biaryls in good to high yields. Up to four phenyl groups were transferred from the organostannanes substrates. The aryls bearing electron-withdrawing groups in either halides or organotin substrates gave coupling products in higher yields. The methodology has been applied for the efficient synthesis of ipriflavones.

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA