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Home > Product > Material & Chemicals > Micro/NanoElectronics > Tetrakis(dimethylamino)zirconium

Tetrakis(dimethylamino)zirconium | CAS Number: 19756-04-8

Catalog Number
ACM19756048
Product Name
Tetrakis(dimethylamino)zirconium
Structure
CAS Number
19756-04-8
IUPAC Name
dimethylazanide; zirconium(4+)
Synonyms
ZIRCONIUM TETRAKIS(DIMETHYLAMIDE);ZIRCONIUM DIMETHYLAMIDE;TETRAKIS(DIMETHYLAMIDO)ZIRCONIUM(IV);TETRAKIS(DIMETHYLAMINO)ZIRCONIUM;TETRAKIS(DIMETHYLAMINO)ZIRCONIUM(IV);TETRAKIS(DIMETHYLAMIDO)ZIRCONIUM(IV), 99.99+%, ELECTRONIC GRADE;TETRAKIS(DIMETHYLAMINO)ZIR
Molecular Weight
267.53
Exact Mass
266.10500
Molecular Formula
C8H24N4Zr
Boiling Point
80ºC 0,1mm
Melting Point
57-60ºC(lit.)
Purity
96%
Appearance
Pale yellow-greenish crystalline solid
SMILES
C[N-]C.C[N-]C.C[N-]C.C[N-]C.[Zr+4]
InChIKey
DWCMDRNGBIZOQL-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
4
Safty Description
16-26-36-43
Hazard Statements
Xi: Irritant;F: Flammable;
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1Novel β-ketoiminato complexes of zirconium: synthesis, characterization and evaluation for solution based processing of ZrO2 thin films.

Banerjee M1, Seidel RW, Winter M, Becker HW, Rogalla D, Devi A.

Dalton Trans. 2014 Feb 14;43(6):2384-96. doi: 10.1039/c3dt52335g. Epub 2013 Dec 3.

Treatment of tetrakis(diethylamido)zirconium(IV); [Zr(NEt2)4] with a series of β-ketoimines ({[RHN]C(CH3)=C(H)C(CH3)=O} where R is a functionalized side-chain; 4-(2-methoxyethylamino)pent-3-en-2-one, Hmeap; 4-(3-methoxypropylamino)pent-3-en-2-one, Hmpap; 4-(2-(dimethylamino)ethylamino)pent-3-en-2-one, Hdeap; 4-(3-(dimethylamino)propylamino)pent-3-en-2-one, Hdpap) leads to an amine substitution reaction that yielded novel monomeric heteroleptic mixed amido-ketoiminato complexes of the type bis(4-(2-methoxyethylamino)pent-3-en-2-onato)bis(diethylamido)zirconium(IV) (1), bis(4-(3-methoxypropylamino)pent-3-en-2-onato)bis(diethylamido)zirconium(IV) (2), and bis(4-(3-(dimethylamino)propylamino)pent-3-en-2-onato)bis(diethylamido)zirconium(IV) (3), and eight-coordinated homoleptic complexes tetrakis(4-(2-methoxyethylamino)pent-3-en-2-onato)zirconium(IV) (4) and tetrakis(4-(2-(dimethylamino)ethylamino)pent-3-en-2-onato)zirconium(IV) (5), depending on the ratio of the ligand to zirconium. Read More

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Tel:1-201-478-8534
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