Frolova LV1, Magedov IV1, Harper A1, Jha SK2, Ovezmyradov M3, Chandler G3, Garcia J3, Bethke D4, Shaner EA4, Vasiliev I2, Kalugin NG5.
Carbon N Y. 2015 Jan 1;81:216-222.The tetracyanoethylene oxide (TCNEO) functionalization of chemical vapor deposition grown large area graphene and graphite was performed using reaction of TCNEO with carbon surface in chlorobenzene. The successful functionalization has been confirmed by Raman and Auger spectroscopy, and by numerical modeling of the structure and vibrational modes of TCNEO-functionalized graphene. Raman spectra of TCNEO-functionalized graphene and graphite show several groups of lines corresponding to vibrations of attached carbonyl ylide. Read More